Sealcoating Specifications

Polymer Modified MasterSeal (PMM) Safety Data Sheet

Polymer-Modified Masterseal – Asphalt Based Pavement Sealer

SAFETY DATA SHEET

Issuing Date: 23-June-2014

Revision Date: 12-June-2017

Revision Number: 3


1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE COMPANY/UNDERTAKING

GHS Product Identifier

Product Name: Polymer Modified MasterSeal (PMM)

Other Means of Identification

Product Code(s): S1097

Synonyms: None

Recommended Use of the Chemical and Restrictions on Use

Recommended Use: No Information Available

Uses Advised Against: No Information Available

Supplier’s Details

Supplier Address

SealMaster
Locations Nationwide
www.sealmaster.net
1-800-341-7325

Manufacturer Address

SealMaster
Locations Nationwide
www.sealmaster.net
1-800-341-7325

Emergency Telephone Number

Chemtrec
1-800-424-9300


2. HAZARDS IDENTIFICATION

Classification

This product is not considered hazardous according to the OSHA Hazard Communication Standard 2012 (29 CFR 1910.1200).

GHS Label Elements, Including Precautionary Statements

Emergency Overview

Signal Word: Warning
• Harmful if swallowed
• May cause skin irritation
Appearance: Black
Physical State: Liquid
Odor: Asphaltic

Precautionary Statements

Prevention:
Inhalation – May cause irritation of respiratory tract.
Eye Contact – Contact with eyes may cause irritation.
Skin Contact – May cause irritation.
Ingestion – Ingestion may cause stomach discomfort.

General Advice: None

Storage: Keep container tightly closed

Disposal: Dispose of material/containers in accordance with the appropriate state, regional, or local regulations.

Hazard Not Otherwise Classified (HNOC)

Not applicable


3. COMPOSITION/INFORMATION ON INGREDIENTS

*The exact percentage of composition has been withheld as a trade secret.
Chemical NameCAS NumberWeight %Trade Secret
Limestone1317-65-320-40*
Water7732-18-5Minimum 50%*
Asphalt8052-42-420-40*
Kaolin1332-58-7Less than 10*
Bentonite1302-78-9Less than 10*

4. FIRST AID MEASURES

Description of Necessary First-Aid Measures

Eye Contact: Rinse thoroughly with plenty of water, also under the eyelids. If symptoms persist, call a physician.
Skin Contact: Wash off immediately with soap and plenty of water. In the case of skin irritation or allergic reactions, see a physician.
Inhalation: Move to fresh air. If symptoms persist, call a physician.
Ingestion: Drink plenty of water. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Consult a physician if necessary.

Most Important Symptoms/Effects, Acute and Delayed

Most Important Symptoms/Effects: No information available

Indication of Immediate Medical Attention and Special Treatment Needed, If Necessary

Notes to Physician: Treat Symptomatically. May cause sensitization by skin contact


5. FIRE-FIGHTING MEASURES

Suitable Extinguishing Media

Carbon Dioxide (CO2). Dry Chemical. Foam. Water Fog.

Unsuitable Extinguishing Media: CAUTION: Use of water spray when fighting fire may be inefficient.

Specific Hazards Arising from the Chemical

No information available

Explosion Data

Sensitivity to Mechanical Impact: None
Sensitivity to Static Discharge: None

Protective Equipment and Precautions for Firefighters

As in any fire, wear self-contained breathing apparatus pressure-demand MSHA/NIOSH (approved or equivalent) and full protective gear.


6. ACCIDENTAL RELEASE MEASURES

Personal Precautions, Protective Equipment, and Emergency Procedures

Personal Precautions: Ensure adequate ventilation. Avoid contact with skin, eyes and clothing. Use personal protective equipment.

Environmental Precautions

Environmental Precautions: See Section 12 for additional Ecological Information

Methods and Materials for Containment and Cleaning Up

Methods for Containment: Prevent further leakage or spillage if safe to do so.
Methods for Cleaning Up: Dam up. Soak up with inert absorbent material. Pick up and transfer to properly labeled containers. Clean contaminated surface thoroughly.


7. HANDLING AND STORAGE

Precautions for Safe Handling

Handling: Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes, and clothing. Wear personal protective equipment. Avoid breathing vapors or mists. Do not eat, drink, or smoke when using this product. Wash thoroughly after handling.

Conditions for Safe Storage, Including Any Incompatibilities

Storage: Keep container tightly closed
Incompatible Products: Strong oxidizing agents. Acids.


8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Control Parameters

Exposure Guidelines

Chemical NameACGIH TLVOSHA PELNIOSH IDLH
Limestone
1317-65-3
TWA: 15 mg/m³
TWA: 5 mg/m³
(vacated) TWA: 15 mg/m³
(vacated) TWA: 5 mg/m³
TWA: 5 mg/m³ respirable dust
TWA 10 mg/m³ total dust
Asphalt
8052-42-4
TWA: 0.5 mg/m³ benzene soluble aerosol fume, inhalable fractionCeiling: 5 mg/m³ fume 15 min.
Kaolin
1332-58-7
TWA: 15 mg/m³ total dust
TWA: 5 mg/m³ respirable fraction
(vacated) TWA: 10 mg/m³ total dust
(vacated) TWA 5 mg/m³ respirable fraction
TWA: 15 mg/m³ total dust
TWA: 5 mg/m³ respirable dust
Bentonite
1302-78-9
TWA 1 mg/m³ respirable fraction

Appropriate Engineering Controls

Engineering Measures: Showers, Eyewash Stations, Ventilation Systems

Individual Protection Measures, such as Personal Protective Equipment

Eye/Face Protection: If splashes are likely to occur, wear: Safety glasses with side shields.
Skin and Body Protection: Impervious gloves.
Respiratory Protection: No protective equipment is needed under normal use conditions. If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn.
Hygiene Measures: Handle in accordance with good industrial hygiene and safety practice.


9. PHYSICAL AND CHEMICAL PROPERTIES

Information on Basic Physical and Chemical Properties

Physical State: Liquid
Appearance: Black
Odor: Asphaltic
Odor Threshold: No Information Available

Property

pH: No data available
Melting Point/Range: No data available
Boiling Point/Boiling Range: 100° C
Flash Point: Above 400° F
Evaporation Rate: No data available
Flammability: Not Flammable
Flammability Limits in Air
Upper flammability limit: Not Flammable
Lower flammability limit: Not Flammable
Vapor Pressure: No data available
Vapor Density: No data available
Specific Density: 1.20@ 77 F
Water Solubility: Easily dispersible
Solubility in other solvents: No data available
Partition coefficient: n-octanol/water: No data available
Autoignition Temperature: Will Not Autoignite
Decomposition Temperature: No data available
Viscosity: No data available
Flammable Properties: Not Flammable
Explosive Properties: Not Explosive
Oxidizing Properties: Not an Oxidizer

Other Information

VOC Content: Less than 15 g/l


10. STABILITY AND REACTIVITY

Reactivity: Non Reactive

Chemical Stability: Stable under recommended storage conditions.

Possibility of Hazardous Reactions: None under normal processing.

Hazardous Polymerization: Hazardous polymerization does not occur.

Conditions to Avoid: None known

Incompatible Materials: Strong oxidizing agents. Acids.

Hazardous Decomposition Products: Carbon Monoxide (CO), Carbon Dioxide (CO²), Hydrogen Sulfide, Nitrogen Dioxide


11. TOXICOLOGICAL INFORMATION

Information on Likely Routes of Exposure

Product Information
Inhalation: May cause irritation of respiratory tract.
Eye Contact: Contact with eyes may cause irritation.
Skin Contact: May cause irritation.
Ingestion: Ingestion may cause stomach discomfort.

Chemical NameLD50 OralLD50 DermalLD50 Inhalation
Asphalt5000 mg/kg (Rat)Greater than 2000 mg/kg (Rabbit)
BentoniteGreater than 5000 mg/kg (Rat)

Symptoms Related to the Physical, Chemical, and Toxicological Characteristics

Symptoms: No information available.

Delayed and Immediate Effects and also Chronic Effects from Short and Long Term Exposure

Sensitization: No information available.
Mutagenic Effects: No information available.
Carcinogenicity: The table below indicates whether each agency has listed any ingredient as a carcinogen. The IARC, NTP, and OSHA do not list asphalt as a carcinogen. In general, the oxidation of polycyclic aromatic hydrocarbons destroys their carcinogenic potential. Petroleum asphalt, shale oil asphalts, and coal tars show distinct variation in their relative carcinogenicity for experimental animals.

Chemical NameACGIHIARCNTPOSHA
AsphaltA3Group 2BResonably AnticipatedX

ACGIH: (American Conference of Governmental Industrial Hygienists)
A3 –Animal Carcinogen

IRAC: (International Agency for Research on Cancer)
Group 2B –Possibly Carcinogenic to Humans

NTP: (National Toxicity Program)
Reasonably Anticipated–Reasonably Anticipated to be a Human Carcinogen

OSHA: (Occupational Safety & Health Administration)
X –Present

Reproductive Toxicity: No information available.
STOT -Single Exposure: No information available.
STOT –Repeated Exposure: No information available.
Aspiration Hazard: No information available.

Numerical Measures of Toxicity –Product

The following values are calculated based on Chapter 3.1 of the GHS document
LD50 Oral: 12542 mg/kg; Acute toxicity estimate
LD50 Dermal: 6181 mg/kg, Acute toxicity estimate


12. ECOLOGICAL INFORMATION

Ecotoxicity

The environmental impact of this product has not been fully investigated.

Chemical NameToxicity to AlgaeToxicity to FishToxicity to MicoorganismsDaphnia Magna (Water Flea)
Bentonite
1302-78-9
LC50 96 h: 8.0-19.0 g/L (Salmo gairdneri)
LC50 96 h: = 19000 mg/L static (Oncorhynchus mykiss)

Persistence and Degradability: No information available.

Bioaccumulation

Chemical NameLog Pow
Asphalt6..006

Other Adverse Effects: No information available.


13. DISPOSAL CONSIDERATIONS

Waste Disposal Methods: This material, as supplied, is not a hazardous waste according to Federal regulations (40 CFR 261). This material could become a hazardous waste if it is mixed with or otherwise comes in contact with a hazardous waste, if chemical additions are made to this material, or if the material is processed or otherwise altered. Consult 40 CFR 261 to determine whether the altered material is a hazardous waste. Consult the appropriate state, regional, or local regulations for additional requirements.

Contaminated Packaging: Do not re-use empty containers.


14. TRANSPORTATION INFORMATION

DOT: Not regulated


15. REGULATORY INFORMATION

International Inventories

TSCA –Complies
DSL/NDSL –Complies

Legend

TSCA –United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL –Canadian Domestic Substances List/Non-Domestic Substances List

U.S. Federal Regulations

Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372:

Chemical NameCAS NumberWeight %SARA 313 – Threshold Values %
Asphalt8052-42-420-400.1

SARA 311/312 Hazard Categories

Acute Health Hazard: No
Chronic Health Hazard: No
Fire Hazard: No
Sudden Release of Pressure Hazard: No
Reactive Hazard: No

Clean Water Act

This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42).

CERCLA

This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific requirements at the local, regional, or state level pertaining to releases of this material.

U.S. State Regulations

California Proposition 65:This product does not contain any Proposition 65 chemicals.

U.S. State Right-To-Know Regulations

“X” designates that the ingredients are listed on the state right to know list.

Chemical NameNew JerseyMassachusettsPennsylvaniaIllinoisRhode Island
LimestoneXXXX
AsphaltXXXX
KaolinXXXX
Carbon BlackXXXXX

U.S. EPA Label Information

EPA Pesticide Registration Number: Not applicable


16. OTHER INFORMATION

NFPA

Health Hazard: 1
Flammability: 0
Instability: 0
Physical and Chemical Hazards – Personal Protections: X

HMIS

Health Hazard: 1
Flammability: 0
Instability: 0
Physical and Chemical Hazards – Personal Protections: X

Revision Date: 12-June-2017
Revision Note: Supercedes 29-July-2015

General Disclaimer

The information provided on this SDS is correct to the best of our knowledge, information, and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation,disposal and release and is not to be considered as a warranty or quality specification. The information relates only to thespecific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text.